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Material Safety Data Sheet
MSDS Report
Shenzhen Herewin Technology Co., Ltd.
Side A, 2 F, A14 Building, No. 26 of Kukengdafu Industrial
Prepared For :
Park, Guanlan Aobei Community, Longhua New District,
Shenzhen City, P.R.C
Product Name:
Polymer Li-ion Battery
Voltage:
Typical
3200mAh, 11.84Wh
Capacity:
Dimension :
125.8mm×42.1mm×6.9mm (L×W×T)
Shenzhen TCT Testing Technology Co., Ltd.
Prepared By :
1F, No.1 Building, No.1 Chongqing Road,
Yibaolai Industrial Park,Qiaotou Village,
Fuyong Town, Baoan District, Shenzhen
Report No.:
TCT140415021M3-1
Date: 2014. 04. 22
Report No.: TCT140415021M3-1 Page 1
This report shall not be reproduced except in full, without the written approval of Shenzhen TCT Testing Technology Co., Ltd.
Material Safety Data Sheet
Material Safety Data Sheet
Section 1- Chemical Product & Company Identification
Product Name: Polymer Li-ion Battery
Manufacture: Shenzhen Herewin Technology Co., Ltd.
Address: Side A, 2 F, A14 Building, No. 26 of Kukengdafu Industrial Park, Guanlan
Aobei Community, Longhua New District, Shenzhen City, P.R.C
Contact Person: Miss Zhao
Tel: +86-0769-82999888
Fax: +86-0769-82993399
Emergency Tel: +86-0769-82999888
Item Code: TCT140415021M3-1
Section 2- Hazards Identification
Preparation
Not dangerous with normal use. Do not dismantle, open or shred Polymer Li-ion
Battery the ingredients contained within or their ingredients products could be harmful.
and
classification
Appearance,
Solid object with no odor, no color.
Color, Odor
Primary
These chemicals are contained in a sealed stainless steel enclosure. Risk of exposure
Route(s)
occurs only if the cell is mechanically, thermally or electrically abused to the point of compromising the enclosure. If this occurs, exposure to the electrolyte solution
of Exposure
contained within can occur by Inhalation, Ingestion, Eye contact and Skin contact
Potential Health ACUTE (short term): see Section 8 for exposure controls In the event that this
Effects:
battery has been ruptured, the electrolyte solution contained within the battery would
be corrosive and can cause burns.
Inhalation: Inhalation of materials from a sealed battery is not an expected route of
exposure. Vapors or mists from a ruptured battery may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed battery is not an expected route of
exposure. Swallowing the contents of an open battery can cause serious chemical
burns of mouth, esophagus, and gastrointestinal tract.
Skin: Contact between the battery and skin will not cause any harm. Skin contact
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Material Safety Data Sheet
with contents of an open battery can cause severe irritation or burns to the skin.
Eye: Contact between the battery and the eye will not cause any harm. Eye contact
with contents of an open battery can cause severe irritation or burns to the eye.
CHRONIC (long term): see Section 11 for additional toxicological data
Conditions
Aggravated
by Exposure
Reported
as carcinogen
Section 3- Composition/Information on Ingredients
Polymer Li-ion Battery is a mixture
Hazardous Ingredients
Concentration or
concentration ranges (%)
Lithium Cobalt Oxide
Polyvinylidene Fluoride
SBR 1.5 9003-55-8
Aluminum packing foil
Labeling according to EC directives.
No symbol and risk phrase are required.
Note: CAS number is Chemical Abstract Service Registry Number.
Report No.: TCT140415021M3-1 Page 3 of 10
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Material Safety Data Sheet
Section 4- First Aid Measures
Inhalation
If contents of an opened battery are inhaled, remove source of contamination or move victim to fresh air. Obtain medical advice.
If skin contact with contents of an open battery occurs, as quickly as possible
remove contaminated clothing, shoes and leather goods. Immediately flush with lukewarm, gently flowing water for at least 30 minutes. If irritation or pain persists, seek medical attention. Completely decontaminate clothing, shoes and leather goods before reuse or discard.
If eye contact with contents of an open battery occurs, immediately flush the
contaminated eye(s) with lukewarm, gently flowing water for at least 30 minutes while holding the eyelids open. Neutral saline solution may be used as soon as it is available. If necessary, continue flushing during transport to emergency care facility. Take care not to rinse contaminated water into the unaffected eye or onto face. Quickly transport victim to an emergency care facility.
Ingestion
If ingestion of contents of an open battery occurs, never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60 to 240 mL (2-8 oz.) of water. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Have victim rinse mouth with water again. Quickly transport victim to an emergency care facility.
Section 5- Fire Fighting Measures
In the event that this battery has been ruptured, the electrolyte solution contain
within the battery would be flammable. Like any sealed container, battery cells may rupture when exposed to excessive heat; this could result in the release of flammable or corrosive materials.
Suitable extinguishing
Use extinguishing media suitable for the materials that are burning.
Unsuitable extinguishing
Sensitivity to Mechanical Impact: This may result in rupture in extreme cases
Sensitivity to Static Discharge: Not Applicable
Fires involving Polymer Li-ion Battery can be controlled with water. When water is
used, however, hydrogen gas may evolve. In a confined space, hydrogen gas can
arising from form an explosive mixture. In this situation, smothering agents are recommended the chemical
to extinguish the fire
As for any fire, evacuate the area and fight the fire from a safe distance. Wear a
pressure-demand, self-contained breathing apparatus and full protective gear.
Fight fire from a protected location or a safe distance. Use NIOSH/MSHA approved
full-face self-contained breathing apparatus (SCBA) with full protective gear.
for firefighters
Health: 0 Flammability: 0 Instability: 0
Report No.: TCT140415021M3-1 Page 4 of 10
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Material Safety Data Sheet
Section 6- Accidental Release Measures
Personal Precautions, protective equipment, and Restrict access to area until completion of emergency procedures
clean-up. Do not touch the spilled material. Wear adequate personal protective equipment as indicated in Section 8.
Environmental Precautions
Prevent material from contaminating soil and from entering sewers or waterways.
Methods and materials for Containment
Stop the leak if safe to do so. Contain the spilled liquid with dry sand or earth. Clean up spills immediately.
Methods and materials for cleaning up
Absorb spilled material with an inert absorbent (dry sand or earth). Scoop contaminated absorbent into an acceptable waste container. Collect all contaminated absorbent and dispose of according to directions in Section 13. Scrub the area with detergent and water; collect all contaminated wash water for proper disposal.
Section 7- Handling and Storage
Don't handling Polymer Li-ion Battery with metalwork. Do not open, dissemble, crush or burn battery. Ensure good ventilation/ exhaustion at the workplace.
Prevent formation of dust.
Information about protection against explosions and fires: Keep ignition sources away- Do not smoke.
If the Polymer Li-ion Battery is subject to storage for such a long term as more than 3 months, it is recommended to recharge the Polymer Li-ion Battery periodically.
3 months: -10℃ +40℃, 45 to 85%RH
And recommended at 0
℃ +35℃ for long period
The capacity recovery rate in the delivery state (50% capacity of fully charged) after storage is assumed to be 80% or more.
The voltage for a long time storage shall be 3.7V 4.2V range.
Do not storage Polymer Li-ion Battery haphazardly in a box or drawer where they may short-circuit each other or be short-circuited by other metal objects.
Keep out of reach of children.
Do not expose Polymer Li-ion Battery to heat or
Report No.: TCT140415021M3-1 Page 5 of 10
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Material Safety Data Sheet
fire. Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic materials.
Section 8 - Exposure Controls/Personal Protection
Engineering Controls
Use local exhaust ventilation or other engineering controls to control sources of dust, mist, fumes and vapor.
Keep away from heat and open flame. Store in a cool, dry place.
Personal Protective Equipment
Respiratory Protection: Not necessary under normal conditions.
Skin and body Protection: Not necessary under normal conditions, Wear neoprene or nitride rubber gloves if handling an open or leaking battery.
Hand protection: Wear neoprene or natural rubber material gloves if handling an open or leaking battery.
Eye Protection: Not necessary under normal conditions, Wear safety glasses if handling an open or leaking battery.
Other Protective Equipment
Have a safety shower and eye wash fountain readily available in the immediate work area.
Hygiene Measures
Do not eat, drink, or smoke in work area. Maintain good housekeeping.
Section 9- Physical and Chemical Properties
Change in condition:
pH, with indication of the concentration
Melting point/freezing point
Boiling Point, initial boiling point and Boiling range:
Upper/lower flammability or explosive limits
Report No.: TCT140415021M3-1 Page 6 of 10
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Material Safety Data Sheet
Vapor Density: (Air = 1)
Density/relative density
Solubility in Water:
n-octanol/water partition coefficient
Auto-ignition temperature
Decomposition temperature
Evaporation rate
Flammability (soil, gas)
Section 10 – Stability and Reactivity
The product is stable under normal conditions.
Conditions to Avoid (e.g. static discharge, shock Do not subject Polymer Li-ion Battery to or vibration)
mechanical shock.
Vibration encountered during transportation does not cause leakage, fire or explosion.
Do not disassemble, crush, short or install with incorrect polarity. Avoid mechanical or electrical abuse.
Incompatible Materials
Hazardous Decomposition Products
This material may release toxic fumes if burned or exposed to fire
Possibility of Hazardous Reaction
Section 11 – Toxicological Information
Risk of irritation occurs only if the cell is mechanically, thermally or electrically abused to the point of compromising the enclosure. If this occurs, irritation to the skin, eyes and respiratory tract may occur.
Sensitization Not
Neurological Effects
Teratogenicity Not
Reproductive Toxicity
Mutagenicity (Genetic Effects)
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Material Safety Data Sheet
Toxicologically Synergistic Materials
Section 12-Ecological Information
Water hazard class 1(Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Anticipated behavior of a chemical product in Not Available environment/possible environmental impact/ ecotoxicity
Mobility in soil
Persistence and Degradability
Bioaccumulation potential
Other Adverse Effects
Section 13 – Disposal Considerations
Product disposal recommendation: Observe local, state and federal laws and regulations.
Packaging disposal recommendation: Be aware discarded batteries may cause fire, tape the battery terminals to insulate them. Don't disassembly the battery. Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local, state and federal laws and regulations.
The potential effects on the environment and human health of the substances used in batteries and accumulators; the desirability of not disposing of waste batteries and accumulators as unsorted municipal waste and of participating in their separate collection so as to facilitate treatment and recycling;
Section 14 – Transport Information
This report applies to by sea, by air and by land;
The Polymer Li-ion Battery (model: P7242125U) tested according to the requirements of the UN manual of tests and Criteria, Part III, subsection 38.3;
The Polymer Li-ion Battery was protected so as to prevent short circuits. This includes protection against contact with conductive materials within the same packaging that could lead to short circuit;
The Polymer Li-ion Battery according to Section II/Section IB of PACKING INSTRUCTION 965, or Section II of PACKING INSTRUCTION 966~967 of the 2014 IATA Dangerous Goods regulations 55th Edition may be transported. and applicable U.S. DOT regulations for the safe transport of Lithium battery.
More information concerning shipping, testing, marking and packaging can be obtained from
label master at http://www.labelmaster.com/. Report No.: TCT140415021M3-1 Page 8 of 10
Hotline: 400-6611-140 Tel: 86-755- 27673339 Fax: 86-755-27673332 http://www.tct-lab.com
Material Safety Data Sheet
The packaging shall be adequate to avoid mechanical damage during transport, handling and
stacking. The materials and pack design shall be chosen so as to prevent the development of
unintentional electrical conduction, corrosion of the terminals and ingress of moisture.
The package must be handled with care and that a flammability hazard exists if the package is damaged;
Each package must be labeled with a Lithium battery handling label or in addition to the Class 9 hazard label.
With regard to transport, the following regulations are cited and considered:
- The International Civil Aviation Organization (ICAO) Technical Instructions.
- The International Air transport Association (IATA) Dangerous Goods Regulations.
UN number of lithium battery: UN3480 or UN3481;
UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment;
UN Classification (Transport hazard class): Non dangerous;
Marine pollutant(Y/N): N;
- The International Maritime Dangerous Goods (IMDG) Code.
For Polymer Li-ion Battery by sea, provided that packaging is strong and prevent the products from
UN number of lithium battery: UN3480 or UN3481;
UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment;
UN Classification (Transport hazard class): Non dangerous;
Marine pollutant(Y/N): Y;
Special Provision: International maritime dangerous goods code (IMDG) 188, 230, 310, 348, 957;
- The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA
- The Office of Hazardous Materials Safety within the US Department of Transportations' (DOT)
Research and Special Programs Administration (RSPA)
Section 15 – Regulatory Information
OSHA hazard communication standard (29 CFR 1910.1200)
Hazardous √ Non-hazardous
Section 16 – Additional Information
The information above is believed to be accurate and represents the best information currently available to
us. however, concorde makes no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. users should make their own investigations to determine the suitability of the information for their particular purposes. although reasonable precautions have been taken in the preparation of the data contained herein, it is offered solely for your information, consideration and investigation. this material safety data sheet provides guidelines for the safe handling and use of this product; it does not and cannot advise on all possible situations, therefore, your specific use of this product should be evaluated to determine if additional precautions are required.
Report No.: TCT140415021M3-1 Page 9 of 10
Hotline: 400-6611-140 Tel: 86-755- 27673339 Fax: 86-755-27673332 http://www.tct-lab.com
Material Safety Data Sheet
The data/information contained herein has been reviewed and approved for general release on the basis
that this document contains no export controlled information.
******End of report******
Report No.: TCT140415021M3-1 Shenzhen TCT Testing Technology Co., Ltd. 1F, Building 1, Yibaolai Industrial Park, Qiaotou Village, Fuyong Town, Baoan District, Shenzhen, Guangdong, P.R.C (518101) Search Number: TCT1404153936M-1 Search System: http://www.tct-lab.com/cn/search.asp Page 10 of 10
Source: http://www.impower.cc/uploadfiles/2015/05/201505271558435843.pdf
Noncollinear magnetic ground state of PrFeAsO This article has been downloaded from IOPscience. Please scroll down to see the full text article. 2011 EPL 93 17003 Download details: IP Address: 128.130.131.2 The article was downloaded on 25/04/2012 at 12:30 Please note that EPL, 93 (2011) 17003 Noncollinear magnetic ground state of PrFeAsO J. Liu , B. Luo , R. Laskowski
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