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Chemwatch australian msds 4753-6

CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
CHEMSET 101 PLUS
SYNONYMS
"Product Code: C101C, C101J, ISKP"
PROPER SHIPPING NAME
POLYESTER RESIN KIT
PRODUCT USE
■ The use of a quantity of material in an unventilated or confined space may result in increased exposure and
an irritating atmosphere developing. Before starting consider control of exposure by mechanical ventilation.
Used according to manufacturer's directions.
SUPPLIER
Company: Ramset Fasteners Pty Ltd
Address:
296- 298 Maroondah Hwy
Mooroolbark
VIC, 3138
Australia
Telephone: 1300 780 063
Telephone: +613 9727 6229
Emergency Tel:1800 039 008
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG
Code.
CHEMWATCH HAZARD RATINGS
• Flammable.
• May cause SENSITISATION by skin contact.
• Harmful to aquatic organisms, may cause long- term adverseeffects in the aquatic environment.
• Do not breathe dust.
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 2 of 12
Section 2 - HAZARDS IDENTIFICATION
• Avoid contact with skin.
• Avoid contact with eyes.
• Wear suitable gloves.
• Wear eye/face protection.
• Use only in well ventilated areas.
• Keep container in a well ventilated place.
• Avoid exposure - obtain special instructions before use.
• To clean the floor and all objects contaminated by this material, use waterand detergent.
• In case of contact with eyes, rinse with plenty of water and contact Doctor orPoisons Information Centre.
• If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (showthis container or label).
• This material and its container must be disposed of as hazardous waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
1- ethylene- 4- methylbenzene [CAS 622- 97- 9] 1- ethylene- 3- methylbenzene [CAS 100- 80- 1] dibenzoyl peroxide 2- ethylhexylbenzoate Section 4 - FIRST AID MEASURES
SWALLOWED
■ - If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to
maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
- Seek medical advice.
EYE
■ If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by
occasionally lifting the upper and lower lids.
- Seek medical attention without delay; if pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
■ If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
■ - If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to
initiating first aid procedures.
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 3 of 12
Section 4 - FIRST AID MEASURES
- Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
- Transport to hospital, or doctor.
NOTES TO PHYSICIAN
■ For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:
- Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.
- Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea,
intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor
arterial blood gases (pO2 50 mm Hg) should be intubated.
- Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of
myocardial injury has been reported; intravenous lines and cardiac monitors should be established in
obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves
clearance.
- A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document
aspiration and detect the presence of pneumothorax.
- Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial
sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the
preferred agents, with aminophylline a second choice.
- Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in
adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
■ Do not use a water jet to fight fire.
FIRE FIGHTING
■ - Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- If safe, switch off electrical equipment until vapour fire hazard removed.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- Avoid spraying water onto liquid pools.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 500 metres in all directions.
FIRE/EXPLOSION HAZARD
■ - Liquid and vapour are flammable.
- Moderate fire hazard when exposed to heat or flame.
- Vapour forms an explosive mixture with air.
- Moderate explosion hazard when exposed to heat or flame.
- Vapour may travel a considerable distance to source of ignition.
- Heating may cause expansion or decomposition leading to violent rupture of containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other pyrolysis products typical of
burning organic material.
FIRE INCOMPATIBILITY
■ - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool
chlorine etc. as ignition may result.
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 4 of 12
Section 5 - FIRE FIGHTING MEASURES
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
■ - Remove all ignition sources.
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb small quantities with vermiculite or other absorbent material.
- Wipe up.
- Collect residues in a flammable waste container.
MAJOR SPILLS
■ - Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- Consider evacuation (or protect in place).
- No smoking, naked lights or ignition sources.
- Increase ventilation.
- Stop leak if safe to do so.
- Water spray or fog may be used to disperse /absorb vapour.
- Contain spill with sand, earth or vermiculite.
- Use only spark-free shovels and explosion proof equipment.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite.
- Collect solid residues and seal in labelled drums for disposal.
- Wash area and prevent runoff into drains.
- If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
■ - Containers, even those that have been emptied, may contain explosive vapours.
- Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of overexposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights or ignition sources.
- Avoid generation of static electricity.
- DO NOT use plastic buckets.
- Earth all lines and equipment.
- Use spark-free tools when handling.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 5 of 12
Section 7 - HANDLING AND STORAGE
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.
SUITABLE CONTAINER
■ - Packing as supplied by manufacturer.
- Plastic containers may only be used if approved for flammable liquid.
- Check that containers are clearly labelled and free from leaks.
- For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where
a can is to be used as an inner package, the can must have a screwed enclosure.
- For materials with a viscosity of at least 2680 cSt. (23 deg. C)
- For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
- Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C)
(i) : Removable head packaging;
(ii) : Cans with friction closures and
(iii) : low pressure tubes and cartridges may be used.
- Where combination packages are used, and the inner packages are of glass, there must be sufficient inert
cushioning material in contact with inner and outer packages
- In addition, where inner packagings are glass and contain liquids of packing group I there must be
sufficient inert absorbent to absorb any spillage, unless the outer packaging is a close fitting moulded
plastic box and the substances are not incompatible with the plastic.
STORAGE INCOMPATIBILITY
■ WARNING:
May decompose violently or explosively on contact with other substances.
- This substance, or one of its components, is one of the relatively few compounds which are described as
"endothermic" i.e. heat is absorbed into the compound, rather than released from it, during its formation.
- The majority of endothermic compounds are thermodynamically unstable and may decompose explosively under
various circumstances of initiation.
- Many but not all endothermic compounds have been involved in decompositions, reactions and explosions and,
in general, compounds with significantly positive values of standard heats of formation, may be considered
suspect on stability grounds.
BRETHERICK L.: Handbook of Reactive Chemical Hazards.
- Avoid reaction with oxidising agents.
Vinyl toluene polymerises explosively unless inhibited with, typically, 10-50 ppm tert-butylcatechol
reacts violently with strong oxidisers, strong acids, peroxides
is incompatible with aluminium chloride, ammonia, aliphatic amines, alkanolamides, caustics, metal salts
uninhibited monomer may block vents and confined spaces by forming a solid polymeric material
STORAGE REQUIREMENTS
■ - Store in original containers in approved flammable liquid storage area.
- Store away from incompatible materials in a cool, dry, well-ventilated area.
- DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
- No smoking, naked lights, heat or ignition sources.
- Storage areas should be clearly identified, well illuminated, clear of obstruction and accessible only to
trained and authorised personnel - adequate security must be provided so that unauthorised personnel do not
have access.
- Store according to applicable regulations for flammable materials for storage tanks, containers, piping,
buildings, rooms, cabinets, allowable quantities and minimum storage distances.
- Use non-sparking ventilation systems, approved explosion proof equipment and intrinsically safe electrical
systems.
- Have appropriate extinguishing capability in storage area (e.g. portable fire extinguishers - dry chemical,
foam or carbon dioxide) and flammable gas detectors.
- Keep adsorbents for leaks and spills readily available.
- Protect containers against physical damage and check regularly for leaks.
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 6 of 12
Section 7 - HANDLING AND STORAGE
- Observe manufacturer's storing and handling recommendations.
In addition, for tank storages (where appropriate):- Store in grounded, properly designed and approved vessels and away from incompatible materials.
- For bulk storages, consider use of floating roof or nitrogen blanketed vessels; where venting to atmosphere is possible, equip storage tank vents with flame arrestors; inspect tank vents during winter conditions for vapour/ ice build-up.
- Storage tanks should be above ground and diked to hold entire contents.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Australia Exposure Standards dibenzoyl peroxide (Benzoyl peroxide) The following materials had no OELs on our records• 2- ethylhexylbenzoate: EMERGENCY EXPOSURE LIMITS
dibenzoyl peroxide 2085- 1 MATERIAL DATA
CHEMSET 101 PLUS:
DIBENZOYL PEROXIDE:
■ For benzoyl peroxide:The recommendation for the TLV-TWA is based on the absence of subjective symptoms of irritation of the nose and throat in humans exposed to 5.25 mg/m3. Whether this is sufficiently low to prevent cumulativeeffects in man is not known.
CHEMSET 101 PLUS: as vinyl tolueneIDLH Level: 5000 ppmThe toxicological properties of vinyltoluene are similar to those of styrene andthe TLV- TWA and STEL are analogous. The limits are thought to be protectiveagainst mucous membrane and ocular irritation and should reduce the complaintsof objectionable odour. Given that axonal degeneration found in rats inhalingvinyltoluene is more significant than in rats inhaling comparable concentrationsof styrene, and that neurological changes are more prominent, the limits are thesubject of review.
Human subjects show ocular and upper respiratory tract irritation at 400 ppm, complain of a strong objectionable odour at 300 ppm and a strong but tolerable odour at 200 ppm. At 50 ppm, the odour isdetectable and may become disagreeable, but does not produce irritation of the mucous membranes.
■ No exposure limits set by NOHSC or ACGIH.
EYE
■ - Safety glasses with side shields.
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 7 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
written policy document, describing the wearing of lens or restrictions on use, should be created for eachworkplace or task. This should include a review of lens absorption and adsorption for the class of chemicalsin use and an account of injury experience. Medical and first-aid personnel should be trained in theirremoval and suitable equipment should be readily available. In the event of chemical exposure, begin eyeirrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the firstsigns of eye redness or irritation - lens should be removed in a clean environment only after workers havewashed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].
HANDS/FEET
■ - Wear chemical protective gloves, eg. PVC.
- Wear safety footwear or safety gumboots, eg. Rubber.
NOTE:
- The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing
gloves and other protective equipment, to avoid all possible skin contact.
- Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
OTHER
■ - Overalls.
- PVC Apron.
- PVC protective suit may be required if exposure severe.
- Eyewash unit.
- Ensure there is ready access to a safety shower.
- Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as
they may produce static electricity.
-
For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets), non sparking safety footwear.
RESPIRATOR
•Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national
equivalent)
The local concentration of material, quantity and conditions of use determine the type of personal protectiveequipment required. For further information consult site specific CHEMWATCH data (if available), or yourOccupational Health and Safety Advisor.
ENGINEERING CONTROLS
■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-
designed engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove
or dilute an air contaminant if designed properly. The design of a ventilation system must match the
particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilationsystem may be required. Ventilation equipment should be explosion-resistant.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Off-white paste with an aromatic odour; not miscible with water.
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 8 of 12
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Does not mix with water.
Sinks in water.
Free- flowing Paste Melting Range (°C) Boiling Range (°C) Solubility in water (g/L) Flash Point (°C) Decomposition Temp (°C) Autoignition Temp (°C) Vapour Pressure (kPa) Upper Explosive Limit (%) Specific Gravity (water=1) Lower Explosive Limit (%) Relative Vapour Density Volatile Component (%vol) Section 10 - STABILITY AND REACTIVITY
CONDITIONS CONTRIBUTING TO INSTABILITY
■ - Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
■ Accidental ingestion of the material may be damaging to the health of the individual.
EYE
■ There is some evidence to suggest that this material can cause eye irritation and damage in some persons.
SKIN
■ There is some evidence to suggest that this material can cause inflammation of the skin on contact in some
persons.
Open cuts, abraded or irritated skin should not be exposed to this material.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury
with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage
is suitably protected.
INHALED
■ Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal
handling, may be damaging to the health of the individual.
There is some evidence to suggest that the material can cause respiratory irritation in some persons. The
body's response to such irritation can cause further lung damage.
The use of a quantity of material in an unventilated or confined space may result in increased exposure and
an irritating atmosphere developing. Before starting consider control of exposure by mechanical ventilation.
CHRONIC HEALTH EFFECTS
■ Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to
the general population.
There has been some concern that this material can cause cancer or mutations but there is not enough data to
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 9 of 12
Section 11 - TOXICOLOGICAL INFORMATION
make an assessment.
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.
There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in somepersons compared to the general population.
Based on experience with animal studies, there is a possibility that exposure to the material may result intoxic effects to the development of the foetus, at levels which do not cause significant toxic effects to themother.
Prolonged or repeated skin contact with benzoyl peroxide may result in allergic skin reactions even atdiluted concentrations. Ingestion results in abdominal pain, low body oxygen and severe depression. Chroniceffects of exposure include allergic reactions characterised by redness, itching, oozing, crusting, andscaling of the skin and asthmatic wheezing. Although it does not exhibit complete carcinogenic or tumour-initiating activity, it has been associated with certain tumours of like papillomas and squamous cellcarcinomas.
There is inadequate evidence in humans for the carcinogenicity of vinyl toluene. There is evidence suggestinglack of carcinogenicity of vinyl toluene in experimental animals.
TOXICITY AND IRRITATION
■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
2-ETHYLHEXYLBENZOATE:CHEMSET 101 PLUS:■ No significant acute toxicological data identified in literature search.
DIBENZOYL PEROXIDE:CHEMSET 101 PLUS:■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke'soedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of thedelayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immunereactions. The significance of the contact allergen is not simply determined by its sensitisation potential:the distribution of the substance and the opportunities for contact with it are equally important. A weaklysensitising substance which is widely distributed can be a more important allergen than one with strongersensitising potential with which few individuals come into contact. From a clinical point of view, substancesare noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.
Oral (rat) LD50: 7710 mg/kg Eye (rabbit): 500 mg/24h - Mild Inhalation (human) TCLo: 12 mg/m³ Skin effects (MAK): very weak Subcutaneous (Rat) LD: 40 mg/kg (@ 50%)Intraperitoneal (Mouse) LD50: 440 mg/kgIntravenous (Rabbit) LD: 16 mg/kg■ The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated orprolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skinredness, swelling, the production of vesicles, scaling and thickening of the skin.
Benzoyl peroxide may cause double vision, breathing problems, excess saliva and tear formation, redness ofthe skin and changes in motor activity. It did not produce blood or biochemical adverse effects, genemutation or evidence of cancer. Repeated oral administration may result in decreased weights of testes andthe newborn.
The substance is classified by IARC as Group 3:NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION
International Agency for Research on Cancer(IARC) - AgentsReviewed by the IARCMonographs Section 12 - ECOLOGICAL INFORMATION
2-ETHYLHEXYLBENZOATE:DIBENZOYL PEROXIDE:■ DO NOT discharge into sewer or waterways.
DIBENZOYL PEROXIDE:■ For benzoyl peroxide:Benzoyl peroxide has a melting point of 104 -106 °C, vapor pre ssure of 0.00929 Pa, solubility of 9.1 mg/L inwater at 25 C, and log Pow of 3.43 at 25 C.
Environmental Fate: For indirect photolysis in the atmosphere, the half-life is estimated to be 3 days. Thesubstance is readily biodegradable and hydrolyses rapidly in water. The main hydrolysis product of benzoylperoxide is benzoic acid. The estimated BCF of 92 suggests that the chemical has a low potential forbioaccumulation. Benzoyl peroxide is most likely to partition to water, where it will remain.
Ecotoxicity: Green algae (Selenastrum capricornutum) EbC50 (72 h): 0.07 mg/L (biomass) and 0.44 mg/L (growthrate).
Daphnia magna: EC50 (48 h): Fish LC50 (96 h): Oryzias latipes 0.24 mg/L.
Microorganism (activated sludge):EC50 (30 min): 35 mg/LThe toxicity observed is assumed to be due to benzoyl peroxide rather than benzoic acid, which shows muchlower toxicity to aquatic organisms. One can assume that effects occur before hydrolysis takes place.
2-ETHYLHEXYLBENZOATE:■ Very toxic to aquatic organisms.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high watermark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
dibenzoyl peroxide 2- ethylhexylbenzoate Section 13 - DISPOSAL CONSIDERATIONS
■ - Containers may still present a chemical hazard/ danger when empty.
- Return to supplier for reuse/ recycling if possible.
Otherwise:- If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
- Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 11 of 12
Section 13 - DISPOSAL CONSIDERATIONS
- Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (after admixture with suitable combustible material).
- Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE LIQUID ADG7:
Class or Division:
Special Provision: Limited Quantity: Portable Tanks & Bulk Portable Tanks & Bulk Containers - Special Packagings & IBCs - Packagings & IBCs - Packing Instruction: Name and Description: POLYESTER RESIN KIT Land Transport UNDG:
Class or division:
UN packing group: Shipping Name:POLYESTER RESIN KIT Air Transport IATA:
ICAO/IATA Class:
ICAO/IATA Subrisk: Special provisions: Cargo OnlyPacking Instructions: Maximum Qty/Pack: Passenger and Cargo Passenger and Cargo Packing Instructions: Maximum Qty/Pack: Passenger and Cargo Passenger and Cargo Packing Instructions: Maximum Qty/Pack: Shipping name:POLYESTER RESIN KIT Maritime Transport IMDG:
IMDG Class:
Special provisions: Limited Quantities: Shipping name:POLYESTER RESIN KIT Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE None CHEMSET 101 PLUS
Chemwatch Independent Material Safety Data Sheet
Issue Date: 25-Nov-2011
Version No:4
CD 2011/4 Page 12 of 12
Section 15 - REGULATORY INFORMATION
Regulations for ingredients
dibenzoyl peroxide (CAS: 94-36-0) is found on the following regulatory lists;
"Australia - South Australia Controlled Substances (Poisons) Regulations - Schedule E: Schedule 2 poisons authorised to be sold by holder of a medicine sellers
licence","Australia Dangerous Goods Code (ADG Code) - List of Currently Assigned Organic Peroxides in Packagings","Australia Exposure Standards","Australia
Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) -
Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","Australia Standard for the Uniform
Scheduling of Medicines and Poisons (SUSMP) - Schedule 2","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4",
"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","International Agency for Research on Cancer (IARC) - Agents
Reviewed by the IARC Monographs","International Air Transport Association (IATA) Dangerous Goods Regulations","International Air Transport Association (IATA)
Dangerous Goods Regulations - Prohibited List"
2-ethylhexylbenzoate (CAS: 5444-75-7) is found on the following regulatory lists;
"FEMA Generally Recognized as Safe (GRAS) Flavoring Substances 24 - Primary Names and Synonyms"
No data for Chemset 101 Plus (CW: 4753-61)
Section 16 - OTHER INFORMATION
Denmark Advisory list for selfclassification of dangerous substances
Substance
2- ethylhexylbenzoate ■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700. Issue Date: 25-Nov-2011Print Date: 28-Nov-2011 This is the end of the MSDS.

Source: http://www.ramset.co.nz/Document/Download/2/1/432/rsc432_20121112125342.pdf/Chemset%20101%20Plus%20MSDS.pdf