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Safety Data Sheet according to Regulation (EC) No1907/2006
SDS No. : 76601 TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Revision: 17.09.2014 printing date: 21.11.2014 SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Contains:
Cyclohexane Ethyl acetate 1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use: Contact adhesive 1.3. Details of the supplier of the safety data sheet
Henkel Technologies (Pty.) Ltd.
Potgieter Street, 1450 Alrode Ext. 4
4534
Johannesburg 2000 1.4. Emergency telephone number
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification (CLP):
Flammable liquids H225 Highly flammable liquid and vapor. H315 Causes skin irritation. Serious eye irritation H319 Causes serious eye irritation. Specific target organ toxicity - single exposure H336 May cause drowsiness or dizziness. Acute hazards to the aquatic environment H400 Very toxic to aquatic life. Chronic hazards to the aquatic environment H410 Very toxic to aquatic life with long lasting effects. TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Classification (DPD):
F - Highly flammable R11 Highly flammable. R36/38 Irritating to eyes and skin. Dangerous for the environment R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. 2.2. Label elements
Label elements (CLP):
Hazard pictogram:
Signal word:
Hazard statement:
H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H410 Very toxic to aquatic life with long lasting effects. Supplemental information
Contains Rosin. May produce an allergic reaction. Precautionary statement:
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Prevention
No smoking. P261 Avoid breathing vapours. P273 Avoid release to the environment. P280 Wear protective gloves/eye protection. Precautionary statement:
P370+P378 In case of fire: Use CO2, dry chemical, or foam for extinction. Response
TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Label elements (DPD):
F - Highly flammable N - Dangerous for the R36/38 Irritating to eyes and skin. R11 Highly flammable. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. S2 Keep out of the reach of children. S16 Keep away from sources of ignition - No smoking. S24/25 Avoid contact with skin and eyes. S33 Take precautionary measures against static discharges. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/Safety data sheets. Contains Rosin. May produce an allergic reaction. 2.3. Other hazards
Solvents contained in the product evaporate during processing and their vapors can form explosive/highly inflammable
air/vapor mixtures.
The solvent vapors are heavier than air and may collect in high concentrations at floor level.
Persons suffering from allergic reactions to colophony should avoid contact with the product.
SECTION 3: Composition/information on ingredients
General chemical description:
Base substances of preparation:
TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Declaration of the ingredients according to CLP (EC) No 1272/2008:
Hazardous components
EC Number
REACH-Reg No.
Aspiration hazard 1 Specific target organ toxicity - single Acute hazards to the aquatic environment 1 Chronic hazards to the aquatic environment 1 Flammable liquids 2 Skin irritation 2 Flammable liquids 2 Specific target organ toxicity - single Serious eye irritation 2 Hydrocarbon aliphatic C4-11 < 0,1% Aspiration hazard 1 Skin irritation 2 Specific target organ toxicity - single Flammable liquids 2 Chronic hazards to the aquatic environment 2 Acute hazards to the aquatic environment 1 Chronic hazards to the aquatic environment 1 Flammable liquids 2 Toxic to reproduction 2 Aspiration hazard 1 Specific target organ toxicity - repeated Skin irritation 2 Specific target organ toxicity - single Chronic hazards to the aquatic environment 2 Skin sensitizer 1 Acute toxicity 4; Oral Specific target organ toxicity - repeated Skin sensitizer 1 Acute hazards to the aquatic environment 1 Chronic hazards to the aquatic environment 1 For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.
TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Declaration of ingredients according to DPD (EC) No 1999/45:
Hazardous components
EC Number
REACH-Reg No.
F - Highly flammable; R11 Xn - Harmful; R65 N - Dangerous for the environment; R50/53 Xi - Irritant; R38 F - Highly flammable; R11 Xi - Irritant; R36 Hydrocarbon aliphatic C4-11 < 0,1% F - Highly flammable; R11 Xi - Irritant; R38 Xn - Harmful; R65 N - Dangerous for the environment; R51/53 N - Dangerous for the environment; R50/53 F - Highly flammable; R11 Toxic for reproduction - category 3.; R62 Xn - Harmful; R65, R48/20 Xi - Irritant; R38 N - Dangerous for the environment; R51/53 Xn - Harmful; R22, R48/22 N - Dangerous for the environment; R50/53 For full text of the R-Phrases indicated by codes see section 16 'Other Information'.
Substances without classification may have community workplace exposure limits available.
SECTION 4: First aid measures
4.1. Description of first aid measures
Fresh air, oxygen supply, warmth; seek specialist medical attention. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed
EYE: Irritation, conjunctivitis.
SKIN: Redness, inflammation.
Vapors may cause drowsiness and dizziness.
An allergic reaction cannot be excluded after repeated skin contact.
4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures SECTION 5: Firefighting measures
TEROSON SB 2444 known as TEROKAL 2444 TB 175GR 5.1. Extinguishing media
Suitable extinguishing media:
All common extinguishing agents are suitable. Extinguishing media which must not be used for safety reasons:
Water jet (solvent-containing product). 5.2. Special hazards arising from the substance or mixture
In case of fire toxic gases can be released. 5.3. Advice for firefighters
Wear protective equipment. Wear self-contained breathing apparatus. SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective equipment.
Avoid contact with skin and eyes.
Danger of slipping on spilled product.
Keep unprotected persons away.
6.2. Environmental precautions
Do not empty into drains / surface water / ground water.
Inform authorities in the event of product spillage to water courses or sewage systems.
6.3. Methods and material for containment and cleaning up
Remove with liquid-absorbing material (sand, peat, sawdust).
Dispose of contaminated material as waste according to Section 13.
6.4. Reference to other sections
See advice in section 8 SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid open flames and sources of ignition.
Ground/bond container and receiving equipment.
Use explosion proof electric equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Take off contaminated clothing and wash before reuse. 7.2. Conditions for safe storage, including any incompatibilities
Ensure good ventilation/extraction.
Store in a cool, frost-free place.
Storage at 10 to 20°C is recommended.
7.3. Specific end use(s)
Contact adhesive TEROSON SB 2444 known as TEROKAL 2444 TB 175GR SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational Exposure Limits
Ingredient
Category
Time Weighted Average Short Term Exposure Time Weighted Average MAGNESIUM OXIDE, FUME AND Short Term Exposure RESPIRABLE DUST (AS MG) 1309-48-4 MAGNESIUM OXIDE, RESPIRABLE Time Weighted Average 1309-48-4 MAGNESIUM OXIDE, FUME AND Time Weighted Average RESPIRABLE DUST (AS MG) 1309-48-4 ZINC OXIDE, FUME Time Weighted Average ZINC OXIDE, FUME Short Term Exposure ROSIN CORE SOLDER PYROLYSIS Time Weighted Average PRODUCTS (AS FORMALDEHYDE) 8050-09-7 ROSIN CORE SOLDER PYROLYSIS Short Term Exposure PRODUCTS (AS FORMALDEHYDE) 8050-09-7 N-HEXANE Time Weighted Average TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Predicted No-Effect Concentration (PNEC):
Name on list
Environmental Exposure
Compartment period
(intermittent releases) 110-82-7 Cyclohexane 110-82-7 Ethyl acetate (intermittent releases) 141-78-6 Ethyl acetate 141-78-6 zinc oxide 1314-13-2 zinc oxide TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Derived No-Effect Level (DNEL):
Name on list
Application
Health Effect
Exposure
Exposure
Acute/short term exposure - local effects Acute/short term exposure - systemic effects exposure - systemic effects exposure - local effects 2016 mg/kg bw/day exposure - systemic effects Acute/short term exposure - systemic effects Acute/short term exposure - local effects 1186 mg/kg bw/day exposure - systemic effects 59,4 mg/kg bw/day exposure - systemic effects exposure - systemic effects exposure - local effects 2016 mg/kg bw/day exposure - systemic effects Acute/short term exposure - systemic effects Acute/short term exposure - local effects exposure - systemic effects exposure - systemic effects exposure - local effects Acute/short term exposure - systemic effects Acute/short term exposure - local effects exposure - systemic effects exposure - systemic effects exposure - systemic effects exposure - local effects Hydrocarbon aliphatic C4-11 < 0,1% TEROSON SB 2444 known as TEROKAL 2444 TB 175GR systemic effects Hydrocarbon aliphatic C4-11 < 0,1% systemic effects Hydrocarbon aliphatic C4-11 < 0,1% systemic effects Hydrocarbon aliphatic C4-11 < 0,1% systemic effects Hydrocarbon aliphatic C4-11 < 0,1% systemic effects exposure - systemic effects exposure - systemic effects exposure - systemic effects exposure - systemic effects 0,83 mg/kg bw/day exposure - systemic effects exposure - systemic effects exposure - systemic effects exposure - systemic effects exposure - systemic effects exposure - systemic effects Biological Exposure Indices:
8.2. Exposure controls:
Engineering controls: Use only in well ventilated areas. Respiratory protection: In case of aerosol formation, we recommend wearing of appropriate respiratory protection equipment with ABEK P2 filter. This recommendation should be matched to local conditions. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Goggles which can be tightly sealed. TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Skin protection: Protective clothing that covers arms and legs. Wear protective equipment. Advices to personal protection equipment: Use only personal protection that's CE-labelled according to the regulation no. 819 of 19 August 1994. SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
No data available / Not applicable No data available / Not applicable Initial boiling point 63,0 °C (145.4 °F) -24 °C (-11.2 °F); DIN 51755 Closed cup flash point Decomposition temperature > 120,0 °C (> 248 °F) (20,0 °C (68 °F)) (55 °C (131 °F)) (55 °C (131 °F)) (20 °C (68 °F)) No data available / Not applicable (Brookfield; Instrument: RVT; 20,0 °C (68 °F); Spindle No: 4) Viscosity (kinematic) No data available / Not applicable Explosive properties No data available / Not applicable Solubility (qualitative) Partially soluble (Solvent: Water) Solidification temperature No data available / Not applicable No data available / Not applicable No data available / Not applicable Auto-ignition temperature No data available / Not applicable Explosive limits Partition coefficient: n-octanol/water No data available / Not applicable Evaporation rate No data available / Not applicable No data available / Not applicable Oxidising properties No data available / Not applicable 9.2. Other information
Ignition temperature > 200,0 °C (> 392 °F) SECTION 10: Stability and reactivity
10.1. Reactivity
Reacts with strong oxidants. 10.2. Chemical stability
Stable under recommended storage conditions. 10.3. Possibility of hazardous reactions
See section reactivity TEROSON SB 2444 known as TEROKAL 2444 TB 175GR 10.4. Conditions to avoid
Heat, flames, sparks and other sources of ignition. 10.5. Incompatible materials
None if used properly. 10.6. Hazardous decomposition products
No decomposition if used according to specifications. SECTION 11: Toxicological information
11.1. Information on toxicological effects
General toxicological information:
The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. STOT-single exposure:
May cause drowsiness or dizziness. Skin irritation:
Causes skin irritation. Eye irritation:
Causes serious eye irritation. Acute oral toxicity:
Hazardous components
Exposure
application
> 5.000 mg/kg > 5.000 mg/kg Acute inhalative toxicity:
Hazardous components
Exposure
application
Acute dermal toxicity:
Hazardous components
Exposure
application
> 2.000 mg/kg > 18.000 mg/kg dermal > 2.000 mg/kg > 2.000 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) > 2.000 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Skin corrosion/irritation:
Hazardous components
Exposure
141-78-6 zinc oxide OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation:
Hazardous components
Exposure
slightly irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization:
Hazardous components
Test type
CAS-No.
Ethyl acetate
Guinea pig guinea pig OECD Guideline 406 (Skin Guinea pig guinea pig OECD Guideline 406 (Skin Germ cell mutagenicity:
Hazardous components
Type of study /
Metabolic
activation /
Exposure time
bacterial reverse with and without mutation assay (e.g Ames test) bacterial reverse with and without mutation assay (e.g Ames test) bacterial reverse with and without mutation assay (e.g Ames test) bacterial reverse with and without OECD Guideline 471 mutation assay (e.g (Bacterial Reverse Mutation Repeated dose toxicity
Hazardous components
Exposure time /
application
Frequency of
treatment
TEROSON SB 2444 known as TEROKAL 2444 TB 175GR SECTION 12: Ecological information
General ecological information:
The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria
for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.
Do not empty into drains, soil or bodies of water.
12.1. Toxicity
Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Hazardous components
Exposure
Toxicity
Leuciscus idus melanotus 203 (Fish, Acute 202 (Daphnia sp. 201 (Alga, Growth Inhibition Test) 201 (Alga, Growth Inhibition Test) Leuciscus idus melanotus Daphnia cucullata 202 (Daphnia sp. Selenastrum capricornutum (new name: Pseudokirchnerella 201 (Alga, Growth Inhibition Test) Selenastrum capricornutum (new name: Pseudokirchnerella 201 (Alga, Growth Inhibition Test) Reproduction Test) Hydrocarbon aliphatic C4-11 > 1 - 10 mg/l < 0,1% benzene 203 (Fish, Acute Hydrocarbon aliphatic C4-11 < 0,1% benzene 202 (Daphnia sp. Hydrocarbon aliphatic C4-11 > 1 - 10 mg/l < 0,1% benzene 201 (Alga, Growth Inhibition Test) 203 (Fish, Acute Selenastrum capricornutum (new name: Pseudokirchnerella 201 (Alga, Growth Inhibition Test) Selenastrum capricornutum (new name: Pseudokirchnerella 201 (Alga, Growth Inhibition Test) > 1 - 10 mg/l 203 (Fish, Acute 202 (Daphnia sp. > 1 - 10 mg/l 201 (Alga, Growth Inhibition Test) Pimephales promelas 203 (Fish, Acute 202 (Daphnia sp. Scenedesmus subspicatus (new name: Desmodesmus Lepomis macrochirus Brachydanio rerio (new name: TEROSON SB 2444 known as TEROKAL 2444 TB 175GR early lite stage 202 (Daphnia sp. Chlorella pyrenoidosa 201 (Alga, Growth Inhibition Test) 12.2. Persistence and degradability
Hazardous components
application
readily biodegradable OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) readily biodegradable OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) readily biodegradable OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) 12.3. Bioaccumulative potential / 12.4. Mobility in soil
Hazardous components
LogKow Bioconcentration Exposure
Temperature
factor (BCF)
OECD Guideline 305 (Bioconcentration: Flow- through Fish Test) OECD Guideline 107 (Partition Coefficient (n- octanol / water), Shake 12.5. Results of PBT and vPvB assessment
Hazardous components
PBT/vPvB
CAS-No.
Cyclohexane
Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. Hydrocarbon aliphatic C4-11 < 0,1% benzene Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. 12.6. Other adverse effects
No data available. SECTION 13: Disposal considerations
13.1. Waste treatment methods
TEROSON SB 2444 known as TEROKAL 2444 TB 175GR Product disposal: In consultation with the responsible local authority, must be subjected to special treatment. The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes
for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We
will be happy to advise you.
08 04 09 Waste adhesives and sealants containing organic solvents or other dangerous substances
SECTION 14: Transport information
UN number
UN proper shipping name
ADHESIVES (Cyclohexane) Transport hazard class(es)
Packaging group
Environmental hazards
Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Special precautions for user
Special provision 640H Tunnelcode: (D/E) Special provision 640H Special provision 640H Transport in accordance with 2.3.2.5 of the IMDG Code. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
TEROSON SB 2444 known as TEROKAL 2444 TB 175GR SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
(VOCV 814.018 VOC regulation CH) VOC Paints and Varnishes (EU):
Product (sub)category: This product is not a subject of the Directive 2004/42/EC 15.2. Chemical safety assessment
A chemical safety assessment has been carried out. SECTION 16: Other information
The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R11 Highly flammable.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R38 Irritating to skin.
R43 May cause sensitisation by skin contact.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62 Possible risk of impaired fertility.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
H225 Highly flammable liquid and vapor.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H361f Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Annex - Exposure Scenarios:
Exposure Scenarios for ethyl acetate can be downloaded under the following link: http://mymsds.henkel.com/mymsds/.490394.en.ANNEX_DE.19414935.0.DE.pdf Alternatively they can be accessed on the internet site www.mymsds.henkel.com by entering number 490394.

Source: http://www.granit-parts.hu/product/datasheet/sdb/SDB-12026_EN_20141203.PDF